Color Characterizations of Pure ZnO and ZnO/ SeO2 Thin Films Annealed at Different Temperature

Document Type : Research Paper

Author

Department of Physics, College of Science, University of Kirkuk, Kirkuk, Iraq

Abstract

Pure Zinc oxide and ZnO/SeO2 oxide thin films were prepared successfully by sol gel method and annealed at different temperature under ambient condition. These films were characterized by means of XRD, AFM, and UV-visible. XRD patterns clearly showed the presence of crystalline ZnO/SeO2 particles, the ZnO/SeO2 film showed a good crystallinity like pure ZnO film, Optical transmittance spectra of films showed high transparency (>87%) in visible region. The color coordinate and tristimulus value of transmittance spectral showed that the best decolourization result was achieved at 7.5 at.% Se at 400oC, 600oC and 10 at.% Se at 500oC , for the best brightness result appeared at two point with 2.5 at.% Se at 600oC and 7.5 at.% Se at 400oC. AFM studies reveal that rms roughness of the thin films increased with the increasing of Se concentrations. Also, the surface roughness increased with the increasing of the annealed temperature.

Keywords

Main Subjects

References

[1]     Pranav Y. Dave, Kartik H. Patel, Kamlesh V. Chauhan, Amit K.., Sushant K. , “Examination of Zinc Oxide Films Prepared By Magnetron Sputtering”, Procedia Technology, 23, 328 (2016).
[2]     Hassiba R., Rafiaa K., Abed M., Mokhtar G. and Faycal D., “Electrodeposition And Characterization of ZnO Thin Films Using Sodium Thiosulfate As An Additive For Photovoltaic Solar Cells”, Journal of Semiconductors , 38(5), 053002 (2017).
 
[3]     Kun T., Bharati T., Ashutosh T., “Growth And Characterization of Zinc Oxide Thin Films on Flexible Substrates at Low Temperature Using Pulsed Laser Deposition”, Vacuum, 146, 483 (2017).
 
[4]     Frank U. H., “Thin Film Zinc Oxide Deposited by CVD and PVD”, Journal of Physics: Conference Series, 764, 012001 (2016).
 
[5]     J. Charlesa, N. Lawrence, S. Thiruvenkadam, ”Structural and Optical Properties of Nanostructured Zinc Oxide Thin Films by Spray Pyrolysis and Ethanol Sensing”, Physics Procedia 49, 92 (2013).
 
[6]     Khadher R., Mazahar F. and Gulam R., “Preparation and characterization of ZnO thin films by Sol-gel method on glass substrates”, International Journal of Current Research, 10, 73689 (2018).
 
[7]     J. Sengupta, R. K. Sahoo, K. K. Bardhan,  C. D. Mukherjee ,”Influence of annealing temperature on the structural, topographical and optical properties of sol–gel derived ZnO thin films”, Materials Letters  65(17-18), 2572 (2011).
 
[8]     Jianzi Li, Jian Xu, Qingbo Xu, Gang Fang, “Preparation and characterization of Al doped ZnO thin films by sol–gel process”, Journal of Alloys and Compounds 542, 151 (2012).
 
[9]     Kai Huang, Zhen Tang, Li Zhang, Jiangyin Yu, Jianguo Lv, Xiansong Liu, Feng Liu, “Preparation and characterization of Mg-doped ZnO thin films by sol–gel method”, Applied Surface Science 258(8), 3710 (2012).
 
[10]  Joydip Sengupta, Arifeen Ahmed, Rini Labar, “Structural and optical properties of post annealed Mg doped ZnO thin films deposited by the sol–gel method”, Materials Letters 109, 265 (2013).
 
[11] Chien-Yie Tsay, Wei-Tse Hsu, “Sol–gel derived undoped and boron-doped ZnO semiconductor thin films: Preparation and characterization”, Ceramics International  39(7), 7425 (2013).
 
[12] Sirirat Tubsungnoen Rattanachan, Phanuwat Krongarrom, Thipwan Fangsuwannarak, “Influence of Annealing Temperature on Characteristics of Bismuth Doped Zinc Oxide Films”, American Journal of Applied Sciences 10(11), 1427 (2013).
 
[13] Yue-Hui Hu, Yi-Chuan Chen, Hai-Jun Xu, Hao Gao, Wei-Hui Jiang, Fei Hu, Yan-Xiang Wang, “Texture ZnO Thin-Films and their Application as Front Electrode in Solar Cells”, Engineering  2, 973 (2010).
 
[14] Yanli Liu, Yufang Li, Haibo Zeng, “ZnO-Based Transparent Conductive Thin Films: Doping, Performance, and Processing”, Journal of Nanomaterials 2013, 9 (2013).
 
[15] J. Tian ,   J. Dai, X. Wang, Y. Yin, P. Wu, “Preparation and characterization of TiO2, ZnO, and TiO2/ZnO nanofilms via sol–gel process”, Journal of Ceramics International  35(6), 2261 (2009).
 
[16] M. H. Habibi, M. K. Sardashti, “Structure and morphology of nanostructured zinc oxide thin films Prepared by dip-vs. spin-coating methods”, Journal of the Iranian Chemical Society 5, 603 (2008).
 
[17] Kurt Nassau, “Color for Science, Art and Technology”, Azimuth, Vol. 1, Amsterdam, Elsevier Science B.V. (1998).
 
[18] Billmeyer and Saltzman, “Principles of color Technology”, 2nd Ed., Wiley Interscience Pub., New York (1981).
Kirkuk Journal of Science
Volume 15, Issue 4
December 2020
Page 107-124

Files

History

  • Receive Date: 05 January 2021
  • Accept Date: 05 January 2021

Share

Export Citation

Statistics