Kirkuk Journal of Science

Kirkuk Journal of Science

Synthesis and Characterization of Pd(II) And Pt(II) Complexes with Bis [Hg (2-Apt)] Compound.

Document Type : Research Paper

Authors
Department of Chemistry, College of Education, Salahaddin University, Erbil, Iraq.
Abstract
The reaction of one mole of Hg(II) acetate with two mole of 2-amino thiophenol gave one mole of [Hg(2-apt)] compound. While the reaction of one mole of [Hg(2-apt)] with two moles of MCL2 salt. Produced new complexes in general formula [M2{Hg(2-apt)Cl4] where M=Pt(II) or Pd(II).All the prepared complexes were identified using FT-IR, 1H-NMR,13C-NMR,elemental analyses (CHNS) and molar conductivity. The results exhibited that metal bounded to the ligand via S and N in squar planer geometries..
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Volume 13, Issue 3
Summer 2018
Page 12-22

  • Receive Date 01 June 2018
  • Revise Date 20 June 2018
  • Accept Date 25 June 2018