Kirkuk Journal of Science

Kirkuk Journal of Science

Synthesis, Characterization of some Transition metal complexes of Piperidine dithiocarbamate and ethylenediamine

Author
Abstract
Piperidine is heterocyclic amine used as starting material for preparation piperidine dithiocarbamate (pipdtc).add the some transition metal salt of this ligand with ethylinediamine gave complexes of the types:[M(pipdtc)2en], [M(pipdtc)3] when the ratio, (M: pipdtc:en,1:2:1), ( M: pipdtc.1:3) respectively . The ligand dithiocarbamate (pipdtc) behaves as a bidentate and coordinated to the metal ion centers either through sulfur atoms and through nitrogen atoms of the ethylenediamine All the synthesized ligand and complexes are characterized by elemental analyses, conductivity, infrared, electronic spectra and susceptibility measurements and theoretical Calculations . From the obtained data octahedral geometry for the complexes have been suggested.
Keywords

Volume 12, Issue 4
Autumn 2017
Page 25-42

  • Receive Date 01 December 2017
  • Revise Date 20 December 2017
  • Accept Date 25 December 2017