Inthis study we describe the synthesis and characterization of four and six coordinated compounds of Mn(II)with Schiff bases derived from vanillin with amino acids (glycine, L-serine, L-tyrosine, and L-phenylalanine).These complexeswere characterized by many physicochemical methods such as elemental analysis(CHN),magnetic susceptibility, molar conductance as well as spectral studies such as IR and UV-Visible .The analytical data showed that the complexes having the formulas[Mn(VA)(H2O)]2,[Mn2(VA)(CH3COO)(H2O)2],whereA-=serineortyrosine[Mn2(Vg)(CH3COO)(H2O)3],[Mn2(VA*H2)2(H2O)2(NO3)2](NO3)2and Na2[Mn2(VA*)2(H2O)2(NO3)2] , A* = all the amino acids .The ligands behave as Tetradentate coordinating through the atomsNOOO, or tridentate NOO; where V= vanillin, A=amino acids (glycine and phenylalanine) that suggested tetrahedral and octahedral geometry.
Jihad Al-Shaheen, A., & Adil Al-Mula, M. (2015). New Dinuclear Schiff Base Complexes of Mn(II) Derived from Amino Acids. Kirkuk Journal of Science, 10(1), 127-142. doi: 10.32894/kujss.2015.101965
MLA
Amira Jihad Al-Shaheen; Miaad Adil Al-Mula. "New Dinuclear Schiff Base Complexes of Mn(II) Derived from Amino Acids". Kirkuk Journal of Science, 10, 1, 2015, 127-142. doi: 10.32894/kujss.2015.101965
HARVARD
Jihad Al-Shaheen, A., Adil Al-Mula, M. (2015). 'New Dinuclear Schiff Base Complexes of Mn(II) Derived from Amino Acids', Kirkuk Journal of Science, 10(1), pp. 127-142. doi: 10.32894/kujss.2015.101965
VANCOUVER
Jihad Al-Shaheen, A., Adil Al-Mula, M. New Dinuclear Schiff Base Complexes of Mn(II) Derived from Amino Acids. Kirkuk Journal of Science, 2015; 10(1): 127-142. doi: 10.32894/kujss.2015.101965
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