تحضیر وتشخیص مرکبات أزو- قواعد شف جدیدة کمواد غنیة بالطاقة واعدة مشتقة من مرکب 1،5- ثنائی أمینو انثراکوینون بطریقة الصهر

نوع المقالة : بحث

المؤلفون

1 قسم الکیمیاء الصیدلیة، کلیة الصیدلة، جامعة کرکوک، کرکوک، العراق.

2 قسم الکیمیاء الصیدلیة، کلیة الصیدلة، جامعة کرکوک، کرکوک، العراق

3 قسم الکیمیاء، کلیة العلوم، جامعة الانبار، الانبار، العراق.

الملخص

یهدف هذا البحث تحضیر مرکبات ازو- قواعد شف غنیة بالطاقة مشتقة من مرکب 1،5- ثنائی أمینو أنثراکوینون وتطویر أطیاف الامتصاص لها لکی تکون جزءا مضافا ومکملا لدراساتنتا السابقة فی مجال تطویر برنامج الخزن الکیمیاوی للطاقة. لقد تم تحضیر خمس مشتقات ازو- قواعد شف من مرکب 1،5- ثنائی أنثراکوینون (An1-An5) بالصهر المعتدل لمیللیول واحد من المرکب المذکور مع مللیمولین من مشتق ازو المحضر من 2- هیدروکسی بنزالدیهاید. تم بتطبیق هذه الطریقة الحصول على منتوج متوسط الى جید. أدى استعمال طریقة الصهرالى تحطیم المادة الاولیة (الازو)، فیما تم استعادة المواد الاولیة بعد ساعات طویلة من التصعید فی مذیب ثنائی مثیل السلفوکسید.

الكلمات الرئيسة

الموضوعات


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