بناء أقطاب جدیدة من الکربون المغلف لتقدیر عقار السیلدینافیل سترات

نوع المقالة : بحث

المؤلفون

1 قسم الکیمیاء، کلیة العلوم، جامعة تکریت، تکریت، العراق.

2 قسم الکیمیاء، کلیة العلوم، جامعة السلیمانیة، السلیمانیة، العراق.

الملخص

فی هذا البحث تم بناء أقطاب جدیدة من الکربون المطلی واستخدمه لتقدیر عقار السیلدینافیل سترات، وتم تصنیع هذه الأقطاب بتحضیر مزدوج أیونی للعقار مع حامض الفوسفوتنکستک أو حامض الفوسفومولیبدیک واستخدام ثنائی بیوتیل الفثالیت کملدن. هذه  الأقطاب أعطت حساسیة جیدة لعقار السیلدینافیل سترات بمدى خطی (10-7- 10-2) مولاری، معامل ارتباط 0.9990، وعمر زمنی 120 یوم، مدى درجة الحرارة المثلى (23-65) درجة مئویة ومدى الدالة مولاری  ومیل (59.10 و57.29) (5. 055´10-8و 5.116´10-8) الحامضیة (2-5) کلا القطبین وحد الکشف لکل من قطب  حامض المولیبدیک و حامض الفوسفوتنکستک على التوالی تم استخدام هذه الأقطاب  mV/decade بنجاح لتقدیر العقار بشکله النقی وفی الحبوب باسترجاعیة لاتقل عن 98%.

الكلمات الرئيسة

الموضوعات


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